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Chiyuu is an artist and is friends with Birthday and Ratio. Her Minimum Holders is making her self blend with the environment like a chameleon. She can also make someone else turn invisible when they are near her. To active her Minimum, she has to say a color.

A hired gun who is a cyborg.

He is an anime-original character, originally the assistant of the machinery development department. Though he and his partners have come up with many ideas about how to make a virtual Embryo or catch the Embryo through X-Eggs, mostly resulted in failures and despised by Kazuomi.

Karen is the oldest member of the team. This third-year student comes from an affluent family and is a member of the student council. Her parents are musicians and often go on tour. She misses them, but will not ask for them to come home for fear of disturbing their work, so despite wealth and popularity, she is often lonely. Komachi is her best friend and a fellow student council member. Seen around school as cool and inspiring, most of the students look up to her. She, as Nozomi learns, is the most trustworthy Cure. In the beginning, she is reluctant to join the Cure team. In episode 6, as the girls are being manhandled, Karen stands up to her friends, vowing to protect them regardless of transformation. The butterfly that eluded her previously reappears and successfully lands on her wrist, enabling her to transform to Cure Aqua. For catching Pinkies, Coco gets a violin from her Pinky Catch. As Cure Aqua; counterpart of Cure Mint, she wears deep blue in her outfit, resembling Cure Mint's outfit. She introduces herself as "Blue Spring of Intelligence, Cure Aqua!" (知性ã�®é�’ã��泉 ã‚ュアアクア!, Chisei no aoki izumi, Kyua Akua!) Like Nozomi and Komachi with Coco and Nuts respectively, she has a special bond with Milk. In the first movie, her counterpart is Dark Aqua, who is voiced by Reiko Kiuchi.

Angie is a recurring character in the anime and a member of Team Plasma. Although Angie wears a uniform standard to a female Team Plasma Grunt, her actions indicate that her position is higher than a simple grunt. Her overall appearance is based on the stock art of the female Team Plasma Grunt from Black 2 and White 2.

Tamama is private second class of the Keroro Platoon. He is the newest member in the planetary invasion troop, and also the youngest. His name stems from the Japanese word otamajakushi "tadpole". While his age is unknown, Etsuko Kozakura has stated that she voiced Tamama as someone who was 19 years old. He is a very faithful subordinate to Keroro. Tamama is possessed of a tendency to have mood swings that border on a split personality, just like his partner Momoka Nishizawa. While usually gentle and cheerful, Tamama can become a vengeful, raving maniac at the drop of a hat[1]. This change is usually accompanied by the sound of a balloon popping. Tamama is also prone to fits of jealousy, usually towards anyone who gets near Keroro (especially Angol Mois, who he frequently refers to as "that woman"). Tamama likes junk food (especially candy, cake, cola, and potato chips) and physical training (he has his own private training room in the Nishizawa Mansion). In the anime, Tamama is diagnosed with high blood sugar because of his love of sweets, as revealed with a physical checkup. Tamama's least favorite sound is nails on a chalkboard. He also dislikes Angol Mois and often calls her "that woman", as he considers her a rival for Keroro's attention. Despite this, Mois seems blissfully unaware of Tamama's hatred towards her.