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The lead character of the series. She is a bubbly girl who has magical powers which she uses only in secret. That is because she is forbidden by her parents to use it. It is only when her cooking teacher Washu discovered her magical powers that they are to be of use. Except for the absence of freckles and the triangular mark on her forehead, she looks similar to her metaseries counterpart.

Akuroma is a researcher from Pokémon Black 2 and White 2. He seemingly takes over control of Team Plasma in its new goal to take over the world. He is also a researcher who focuses on the innate abilities of Pokémon. (Source: Wikipedia)

The third member of the club, she has the ability to either shrink or enlarge herself at will. It is for this (and her short stature) that she drinks up the school's entire supply of milk and eventually goes to the restroom.

Cheren is one of the player character's childhood friends who often battles the player throughout his or her Pokemon journey. Cheren is very knowledgeable about Pokemon and helps the player whenever he can. His name means black in Bulgarian.

N is an enigma of a character who was first introduced in the Black and White, or Fifth generation, Pokémon games. He is one of the rival characters to the player character in the Pokémon games, and appears numerous times to battle with the player. N is an idealistic activist that has adopted the Team Plasma philosophy of releasing Pokémon from human control, due to humanity’s constant abuse of Pokémon and their powers for battle and other practical uses. N’s ideal goal is to create separate worlds for both Pokémon and humans. N has the ability to sense a Pokémon’s feelings and thoughts along with hearing their "voice." He has a very intuitive relationship with Pokémon, more so than he does with actual human beings. N also has an obsession with mathematical formulas and how they work together so cohesively to create many things. In fact, one of his favorite things to do is riding Ferris wheels, simply because he loves how all these different mathematical formulas come together to create a beautifully synchronized circular motion in the Ferris wheel. He later reveals himself to be the leader, or "King," of Team Plasma at the Nimbasa Amusement Park to White(Manga) and to the Player (BW Games) in an attempt to distract White/The Player as some Team Plasma members escape. N becomes the primary antagonist for a majority of the story, as Team Plasma advances in their goal to release all Pokémon from human control.

Kanako's stepsister

Duchess of Romagna, who accedes to the throne after a day of adventure in Roma with Ensign Francesca Lucchini. As head of state does all she can to help the witches of the 501st. Based on the last queen of Italy, Marie José of Belgium.