The popular but sweet guy of the class type, as well as handsome. Jun has strong morals and determined to win Machi's love. He likes her because she is interesting and sees him as a person rather than his looks...unlike the other girls he has met. He also cares deeply for his older sister. Although he confessed to Maachi and was rejected, he is still determined to win her love.
Marilla's brother, a shy, awkward man who takes a liking to Anne from the start. The two become fast friends. He is far less talkative than Anne, but is a very good listener. He also sometimes lets Anne have things which Marilla considers too frivolous, such as a dress with puffed sleeves.
The minister and his wife, two friends for Anne. Mrs. Allan becomes one of Anne's best friends.
The first person Neko befriended from Moritaka academy. Miiko has wavy blue hair done up in two high ponytails, and is described by Neko to have eyes the colour of a beautiful ocean. Miiko is rather quiet and unsocialable, but is quite friendly towards her friends. She is actually a cat and dislikes others who are not her kind, often slapping them or yelling at them when they come too close to her. She is good friends with Neko, whom she affectionately nicknames "Fune", and often becomes jealous when Neko becomes friends with others. She is able to tell which animals people are by smell, and loves Neko's scent, whom she considers comforting. Miiko has a purse that she always put on. Almost most of the time, she never removes the purse even when she's sleeping and it was given to her by her beloved master. She came to Animal Academy to live as a human and finally say to her master that she liked him. Throughout the series, Miiko becomes more independent.