A man who Sasami meets on her trip to the world of the witches. He seems to have already known Sasami when she first met him, he claims it's because he knows her shadow. Sasami finds herself to be very fond of him, and thinks often of him after their encounter.
She is the leader of the "Shining Star" magic girl team. Misao looks at Ayane as a mentor.
The lead character of the series. She is a bubbly girl who has magical powers which she uses only in secret. That is because she is forbidden by her parents to use it. It is only when her cooking teacher Washu discovered her magical powers that they are to be of use. Except for the absence of freckles and the triangular mark on her forehead, she looks similar to her metaseries counterpart.
Akuroma is a researcher from Pokémon Black 2 and White 2. He seemingly takes over control of Team Plasma in its new goal to take over the world. He is also a researcher who focuses on the innate abilities of Pokémon. (Source: Wikipedia)
The fifth member of the club. Although popular with the boys, she has admiration for Tsukasa due to reasons unknown, and does not want anyone to hang out with Tsukasa. She can do drawings and write words and also has the ability to make each of those those words into tangible symbols. Although she acts like a princess, she actually comes from a rather large family with a lot of siblings.
The fourth member of the club. Although almost emotionless, she has the ability to use and manipulate the wind. She has a wealthy, overprotective father who does not want her to use her powers after her mother died, but he eventually lets go of that trait, knowing those powers she have are a reminder of her mother.
Sasami and Misao's homeroom teacher. Just like her counterpart in the Tenchi franchise, she is clumsy and goofs up a lot.