Cooking teacher and adviser of the magical girls' club (and of the cooking club). Although she is recruited by the school, she is in fact from the world of the witches. As advisor, she trains the girls to be good magical girls. Ironically, although she is the cooking teacher, she herself cannot cook. Other than the red rather than green eyes, fans of the Tenchi Muyo! franchise can recognize this character as the Washu they know.
The second member of the magical girl club whom Sasami befriended. She comes off as an introvert because she attracts worm-like creatures around her whenever she gets scared and they envelop her body, making her scary to those around her. It is only after meeting Sasami that she becomes more outgoing. Except for the bow on her hair and her hair being more purple than purplish black, she resembles Misao Amano.
A man who Sasami meets on her trip to the world of the witches. He seems to have already known Sasami when she first met him, he claims it's because he knows her shadow. Sasami finds herself to be very fond of him, and thinks often of him after their encounter.
She is the leader of the "Shining Star" magic girl team. Misao looks at Ayane as a mentor.
The lead character of the series. She is a bubbly girl who has magical powers which she uses only in secret. That is because she is forbidden by her parents to use it. It is only when her cooking teacher Washu discovered her magical powers that they are to be of use. Except for the absence of freckles and the triangular mark on her forehead, she looks similar to her metaseries counterpart.
Akuroma is a researcher from Pokémon Black 2 and White 2. He seemingly takes over control of Team Plasma in its new goal to take over the world. He is also a researcher who focuses on the innate abilities of Pokémon. (Source: Wikipedia)
The fifth member of the club. Although popular with the boys, she has admiration for Tsukasa due to reasons unknown, and does not want anyone to hang out with Tsukasa. She can do drawings and write words and also has the ability to make each of those those words into tangible symbols. Although she acts like a princess, she actually comes from a rather large family with a lot of siblings.